Exploring the Fascinating World of Organometallics and the Grignard Reagent
Delve into the significance of Organometallics, with a focus on Sections 12.4 and 12.5, and discover the revolutionary impact of the Grignard Reagent in advancing organic chemistry. Learn about Victor Grignard's Nobel Prize-winning discovery and the diverse applications of the Grignard Reagent in various chemical reactions.
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Presentation Transcript
Organometallics Sections 12.4 and 12.5
The Grignard Reagent The Nobel Prize in Chemistry 1912 "for the discovery of the so-called Grignard reagent, which in recent years has greatly advanced the progress of organic chemistry" Victor Grignard
The Grignard Reagent X = Cl, Br, I R = methyl 1 , 2 , 3 alkyl vinyl alkynyl aryl
The Grignard Reagent d+ X = Cl, Br, I R = methyl 1 , 2 , 3 alkyl vinyl alkynyl aryl
The Grignard Reagent d+ +2 X = Cl, Br, I R = methyl 1 , 2 , 3 alkyl vinyl alkynyl aryl
The Grignard Reagent d+ +2 -1 X = Cl, Br, I R = methyl 1 , 2 , 3 alkyl vinyl alkynyl aryl
The Grignard Reagent d+ +2 -1 -1 X = Cl, Br, I R = methyl 1 , 2 , 3 alkyl vinyl alkynyl aryl
The Grignard Reagent d+ X = Cl, Br, I R = methyl 1 , 2 , 3 alkyl vinyl alkynyl aryl
The Grignard Reagent X = Cl, Br, I R = methyl 1 , 2 , 3 alkyl vinyl alkynyl aryl
The Grignard Reagent X = Cl, Br, I R = methyl 1 , 2 , 3 alkyl vinyl alkynyl aryl
The Grignard Reagent X = Cl, Br, I R = methyl 1 , 2 , 3 alkyl vinyl alkynyl aryl
The Grignard Reagent X = Cl, Br, I R = methyl 1 , 2 , 3 alkyl vinyl alkynyl aryl
Professor Henry Gilman (May 9, 1893 Nov 7, 1986). Born in Boston, Massachusetts, he received his B. S. (1915), an M. S. (1916), and a Ph.D. (1918) in Chemistry from Harvard University. For his pre-doctoral work he studied in Europe at Zurich Polytechnikum, the Sorbonne in Paris, and at Oxford in London. Dr. Gilman began his career at the University of Illinois as an Instructor of Chemistry in 1919. Later that year, he accepted the position of Assistant Professor (1919 - 1920) at Iowa State College (University). By 1923 Dr. Gilman had been promoted to full Professor teaching all the Organic Chemistry courses at Iowa State College. His main area of research was in the Organometallic Chemistry area of Grignard reagents where he developed numerous Organometallic reagents, including the dialkyllithium reagent which bears his name. http://www.lib.iastate.edu/spcl/exhibits/150/template/gilman.html
The Suzuzi Miyaura Cross Coupling The Nobel Prize in Chemistry 2010 The Nobel Prize in Chemistry 2010 "for palladium-catalyzed cross couplings in organic synthesis" Richard F. Heck Ei-ichi Negishi Akira Suzuki
The Suzuzi Miyaura Cross Coupling Used in preparation of biaryls
The Suzuzi Miyaura Cross Coupling Used in preparation of biaryls
The Suzuzi Miyaura Cross Coupling Used in preparation of biaryls
The Sonogashira Cross Coupling Used in preparation of arylalkynes
The Sonogashira Cross Coupling Used in preparation of arylalkynes
The Sonogashira Cross Coupling Used in preparation of arylalkynes
The Sonogashira Cross Coupling Used in preparation of arylalkynes
